HOME PAGE tiaras, cambridge, lincoln, uk, cambridgeshire, lincolnshire, wedding, jewellery, bridal, designer, cheap, budget, sterling, silver, elven, headdresses, medieval, jewellery cambridge
Turquoise is an opaque blue/green hydrated copper aluminium phosphate mineral according to the chemical formula CuAl6(PO4)4(OH)8·5H2O. It is rare and valuable in finer grades and has been enjoyed as a gem and ornamental stone for thousands of years owing to its unique hue. In recent times turquoise like most other opaque gems has had its popularity undermined by the introduction of treatments, imitations, and synthetics onto the market, some difficult to detect even by experts. The word turquoise is very old and likely is derived from the French pierre turquoise, meaning Turkish stone. This is thought to have arisen from a misconception: turquoise does not occur in Turkey but was traded there, and the gem became associated with the country in the West. Even the finest of turquoise is fracturable, reaching a maximum hardness of just under 6, or slightly more than window glass. Characteristically a cryptocrystalline mineral, turquoise almost never forms single crystals and all of its properties are highly variable. Its crystal system is proven to be triclinic via X-ray diffraction testing. With lower hardness comes lower specific gravity (high 2.90, low 2.60) and greater porosity: These properties are dependent on grain size. The lustre of turquoise is typically waxy to subvitreous, and transparency is usually opaque, but may be semitranslucent in thin sections. Colour is as variable as the mineral's other properties, ranging from white to a powder blue to a sky blue, and from a blue-green to a yellowish green. The blue is attributed to idiochromatic copper while the green may be the result of either iron impurities (replacing aluminium) or dehydration. The refractive index of turquoise is approximately 1.61 or 1.62; this is a mean value seen as a single reading on a gemmological refractometer, owing to the almost invariably polycrystalline nature of turquoise. A reading of 1.61 - 1.65 (birefringence 0.040, biaxial positive) has been taken from rare single crystals. An absorption spectrum may also be obtained with a hand-held spectroscope, revealing a line at 432 nanometres and a weak band at 460 nanometres. Under longwave ultraviolet light, turquoise may occasionally fluoresce green, yellow or bright blue; it is inert under shortwave ultraviolet and X-rays. Turquoise is infusible in all but heated hydrochloric acid. Its streak is a pale bluish white and its fracture is conchoidal, leaving a waxy lustre. Despite its low hardness relative to other gems, turquoise takes a good polish. Turquoise may also be peppered with flecks of pyrite or interspersed with dark, spidery limonite veining. As a secondary mineral, turquoise apparently forms by the action of percolating acidic aqueous solutions during the weathering and oxidation of pre-existing minerals. For example, the copper may come from primary copper sulfides such as chalcopyrite or from the secondary carbonates malachite or azurite; the aluminium may derive from feldspar; and the phosphorus from apatite. Climate factors appear to play an important role as turquoise is typically found in arid regions, filling or encrusting cavities and fractures in typically highly altered volcanic rocks, often with associated limonite and other iron oxides. In the American southwest turquoise is almost invariably associated with the weathering products of copper sulfide deposits in or around potassium feldspar bearing porphyritic intrusives. In some occurrences alunite, potassium aluminium sulfate, is a prominent secondary mineral. Typically turquoise mineralization is restricted to a relatively shallow depth of less than 20 m, although it does occur along deeper fracture zones where secondary solutions have greater penetration. |